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The solvothermal reaction of MnCl2·H2O and 5-methoxybenzene-1,3-dicarboxylic acid (MeO-m-H2BDC) led to a three-dimensional Mn(II) metal-organic framework, namely poly[(dimethylformamide-κO)(μ4-5-methoxybenzene-1,3-dicarboxylato-κ(4)O(1):O(1'):O(3),O(3'):O(3))manganese(II)], [Mn(C9H6O5)(C3H7NO)]n or [Mn(MeO-m-BDC)(DMF)]n (DMF is dimethylformamide). The Mn(II) atom is six-coordinated and exhibits a distorted octahedral geometry formed by five carboxylate O atoms from four different MeO-m-BDC(2-) anionic ligands and by one DMF O atom. The three-dimensional framework of (I) formed by the bridging MeO-m-BDC(2-) ligands and the Mn(II) atoms exhibits a pts topological network when MeO-m-BDC(2-) and Mn(II) are viewed as four-connected nodes.


Xiao-Hui Huang. A three-dimensional manganese(II) metal-organic framework based on 5-methoxybenzene-1,3-dicarboxylic acid and exhibiting a pts net. Acta crystallographica. Section C, Crystal structure communications. 2013 May;69(Pt 5):483-5

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PMID: 23629896

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