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Ferric chloride-graphite intercalation compounds (FeCl3 -GICs) with stage 1 and stage 2 structures were synthesized by reacting FeCl3 and expanded graphite (EG) in air in a stainless-steel autoclave. As rechargeable Li-ion batteries, these FeCl3 -GICs exhibit high capacity, excellent cycling stability, and superior rate capability, which could be attributed to their unique intercalation features. This work may enable new possibilities for the fabrication of Li-ion batteries. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.


Lili Wang, Yongchun Zhu, Cong Guo, Xiaobo Zhu, Jianwen Liang, Yitai Qian. Ferric chloride-graphite intercalation compounds as anode materials for Li-ion batteries. ChemSusChem. 2014 Jan;7(1):87-91

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PMID: 24339264

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