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β-Functionalization of carboxylic anhydrides with β-alkyl substituents through carbene organocatalysis.
Zhichao Jin, Shaojin Chen, Yuhuang Wang, Pengcheng Zheng, Song Yang, Yonggui Robin Chi
Angewandte Chemie (International ed. in English) 2014 Dec 1Sizes of these terms reflect their relevance to your search.
The first NHC-catalyzed functionalization of carboxylic anhydrides is described. In this reaction, the β carbon behaves as a nucleophilic carbon and undergoes asymmetric reactions with electrophiles. Anhydrides with challenging β-alkyl substituents work effectively. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Zhichao Jin, Shaojin Chen, Yuhuang Wang, Pengcheng Zheng, Song Yang, Yonggui Robin Chi. β-Functionalization of carboxylic anhydrides with β-alkyl substituents through carbene organocatalysis. Angewandte Chemie (International ed. in English). 2014 Dec 1;53(49):13506-9
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PMID: 25284248
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