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Access to coumarins by rhodium-catalyzed oxidative annulation of aryl thiocarbamates with internal alkynes.
Yingwei Zhao, Feng Han, Lei Yang, Chungu Xia
Organic letters 2015 Mar 20
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A Rh-catalyzed annulation of aryl thiocarbamates with internal alkynes via C-H bond activation has been developed. This protocol provides a new route to 3,4-disubstituted coumarins.
Citation
Yingwei Zhao, Feng Han, Lei Yang, Chungu Xia.
Access to coumarins by rhodium-catalyzed oxidative annulation of aryl thiocarbamates with internal alkynes.
Organic letters.
2015 Mar 20;17(6):1477-80
Mesh Tags
Alkynes
Catalysis
Coumarins
Cyclization
Molecular Structure
Oxidation-Reduction
Rhodium
Thiocarbamates
Substances
Alkynes
Coumarins
Thiocarbamates
Rhodium
PMID: 25760673
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