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A heterogeneous catalyst made of well-defined Co3 O4 hexagonal platelets with varied exposed facets is coupled with [Ru(bpy)3 ]Cl2 photosensitizers to effectively and efficiently reduce CO2 under visible-light irradiation. Systematic investigation based on both experiment and theory discloses that the exposed {112} facets are crucial for activating CO2 molecules, giving rise to significant enhancement of photocatalytic CO2 reduction efficiency. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Citation

Chao Gao, Qiangqiang Meng, Kun Zhao, Huajie Yin, Dawei Wang, Jun Guo, Shenlong Zhao, Lin Chang, Meng He, Qunxiang Li, Huijun Zhao, Xingjiu Huang, Yan Gao, Zhiyong Tang. Co3 O4 Hexagonal Platelets with Controllable Facets Enabling Highly Efficient Visible-Light Photocatalytic Reduction of CO2. Advanced materials (Deerfield Beach, Fla.). 2016 Aug;28(30):6485-90


PMID: 27171564

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