Structure organization and magnetic properties of microscale ferrogels: The effect of particle magnetic anisotropy.

The equilibrium structure and magnetic properties of a ferrogel object of small size (microferrogel(MFG)) are investigated by coarse-grained molecular dynamics. As a generic model of a microferrogel (MFG), a sample with a lattice-like mesh is taken. The solid phase of the MFG consists of magnetic (e.g., ferrite) nanoparticles which are mechanically linked to the mesh making some part of its nodes. Unlike previous models, the finite uniaxial magnetic anisotropy of the particles, as it is the case for real ferrogels, is taken into account. For comparison, two types of MFGs are considered: MFG-1, which dwells in virtually non-aggregated state independently of the presence of an external magnetic field, and MFG-2, which displays aggregation yet under zero field. The structure states of the samples are analyzed with the aid of angle-resolved radial distribution functions and cluster counts. The results reveal the crucial role of the matrix elasticity on the structure organization as well as on magnetization of both MFGs. The particle anisotropy, which plays insignificant role in MFG-1 (moderate interparticle magnetodipole interaction), becomes an important factor in MFG-2 (strong interaction). There, the restrictions imposed on the particle angular freedom by the elastic matrix result in notable diminution of the particle chain lengths as well as the magnetization of the sample. The approach proposed enables one to investigate a large variety of MFGs, including those of capsule type and to purposefully choose the combination of their magnetoelastic parameters.

Citation

Aleksandr V Ryzhkov, Petr V Melenev, Maria Balasoiu, Yuriy L Raikher. Structure organization and magnetic properties of microscale ferrogels: The effect of particle magnetic anisotropy. The Journal of chemical physics. 2016 Aug 21;145(7):074905

PMID: 27544124

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