Palm olein-in-water Pickering emulsion stabilized by Fe3O4-cellulose nanocrystal nanocomposites and their responses to pH.

We studied the formation of palm olein-in-water (O/W) Pickering emulsion stabilized by Fe3O4-cellulose nanocrystals (MCNC) nanocomposites obtained by ultrasound assisted in-situ co-precipitation method. The synthesized MCNC nanocomposites successfully stabilized Pickering emulsion with dual responses. The magnetic tests revealed a direct-relation between attractability of MCNC-stabilized Pickering emulsions and the emulsion droplet diameter. The Pickering emulsions were stable under pH ranging from 3 to 6. The stability substantially reduced around pH 8-10, and regained slowly when approaching pH 13. From microscopic and mastersizer analysis, monodisperse emulsion droplets were noticed at pH 3-6, and 13, while polydisperse emulsion were obtained at pH 8-12. The Pickering emulsions prepared at pH 6 are stable up to 14 days, while Pickering emulsions at pH 8 experienced coalescence. In this study, the dual stimuli-responsive Pickering emulsion stabilized by MCNC may hold potentials for biomedical and drug delivery as new generation of smart nanotherapeutic carrier. Copyright © 2016 Elsevier Ltd. All rights reserved.

Citation

Liang Ee Low, Beng Ti Tey, Boon Hoong Ong, Eng Seng Chan, Siah Ying Tang. Palm olein-in-water Pickering emulsion stabilized by Fe3O4-cellulose nanocrystal nanocomposites and their responses to pH. Carbohydrate polymers. 2017 Jan 02;155:391-399

PMID: 27702526

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