Basicity of Very Weak Bases in 1,2-Dichloroethane.

The basicity scale of very weak bases has been set up in 1,2-dichloroethane to give, for the first time, reliable quantitative insights into the basic properties of weak bases in a low-polarity solvent. The scale contains 30 compounds, including anilines; phosphanes, and carbonyl bases, such as esters and amides, linked by 53 relative basicity measurements. The scale spans more than 12 pKip units, expanding to as low pKip values as possible with our current experimental methodology. © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Citation

Karl Kaupmees, Robert Järviste, Ivo Leito. Basicity of Very Weak Bases in 1,2-Dichloroethane. Chemistry (Weinheim an der Bergstrasse, Germany). 2016 Nov 21;22(48):17445-17449

PMID: 27766685

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