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Two tripodal squaramide conjugates having 4-(trifluoromethyl)phenyl and 3,5-bis(trifluoromethyl)phenyl substituents were synthesized and found to exhibit highly efficient transmembrane anion transport with the EC50 values being 0.14 and 0.75mol%, respectively. Though one of them has been reported to act as a strong anion receptor, in particular for sulfate anions, these two compounds exhibit no significant selectivity with respect to the tested monovalent anions and a very low level of activity in the presence of sulfate anions. Copyright © 2017 Elsevier Ltd. All rights reserved.


Xiong-Jie Cai, Zhi Li, Wen-Hua Chen. Tripodal squaramide conjugates as highly effective transmembrane anion transporters. Bioorganic & medicinal chemistry letters. 2017 May 01;27(9):1999-2002

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PMID: 28325602

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