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Novel chemical probes for the investigation of nonribosomal peptide assembly.

Y T Candace Ho, Daniel J Leng, Francesca Ghiringhelli, Ina Wilkening, Dexter P Bushell, Otto Kostner, Elena Riva, Judith Havemann, Daniele Passarella, Manuela Tosin

Chemical communications (Cambridge, England) 2017 Jun 27


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    Chemical probes were devised and evaluated for the capture of biosynthetic intermediates involved in the bio-assembly of the nonribosomal peptide echinomycin. Putative intermediate peptide species were isolated and characterised, providing fresh insights into pathway substrate flexibility and paving the way for novel chemoenzymatic approaches towards unnatural peptides.

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    Y T Candace Ho, Daniel J Leng, Francesca Ghiringhelli, Ina Wilkening, Dexter P Bushell, Otto Kostner, Elena Riva, Judith Havemann, Daniele Passarella, Manuela Tosin. Novel chemical probes for the investigation of nonribosomal peptide assembly. Chemical communications (Cambridge, England). 2017 Jun 27;53(52):7088-7091

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    PMID: 28627528

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