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    One-step solid state reaction method was proposed for the first time to realize the transformation of the Zn-containing EAFD from hazardous solid waste to multi-metal doped ferrite with enhanced magnetic property. The effect of Zn-containing EAFD to NiCl2·6H2O mass ratio (RZE/N, g·g-1) on the phases transformation was investigated by X-ray diffraction (XRD), Scanning electron microscopy (SEM) and Raman spectroscopy. The as-synthesized samples were treated by toxicity characteristic leaching procedure (TCLP). It is shown that the TCPL played a key role in determining both the purity and toxicity of the obtained ferrites. The pure metal doped Ni-Zn ferrite with higher saturation magnetization (Ms, 56.8 emu·g-1) and lower coercivity (Hc, 58.5Oe) was gained under the optimum conditions. And the pure ferrite was a green product according to the TCLP and EN12457 standards. Moreover, the evaluation of environmental impact and the recovery ratio of the dust were also discussed. Copyright © 2017. Published by Elsevier B.V.

    Citation

    Hui-Gang Wang, Mei Zhang, Min Guo. Utilization of Zn-containing electric arc furnace dust for multi-metal doped ferrite with enhanced magnetic property: From hazardous solid waste to green product. Journal of hazardous materials. 2017 Oct 05;339:248-255


    PMID: 28654789

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