A solvothermal reaction of SnCl4ยท5H2O, Mn and Se in ethanolamine (Hea) yielded a novel 2-D Mn selenidostannate(iv) [Mn7(ea)6(SnSe4)2]n (1), which not only provides the first example of the incorporation of a hepta-nuclear Mn cluster [Mn7(ea)6]8+ into a selenidostannate(iv) framework, but also shows unusual spin canting behavior.
Jian Zhou, Hong Xiao, Hua-Hong Zou, Xing Liu. A novel 2-D Mn selenidostannate(iv) incorporating high-nuclear Mn clusters with spin canting behavior. Dalton transactions (Cambridge, England : 2003). 2017 Nov 09
PMID: 29120468
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