Zachary X Giustra, Xinyu Yang, Min Chen, Holger F Bettinger, Shih-Yuan Liu
Angewandte Chemie (International ed. in English) 2019 Dec 19We provide a seminal example of the utility of the 1,2-azaborine motif as a 4C+1N+1B synthon in organic synthesis. Specifically, conditions for the practically scalable photoisomerization of 1,2-azaborine in a flow reactor are reported that furnish aminoborylated cyclobutane derivatives. The C-B bonds could also be functionalized to furnish a diverse set of highly substituted cyclobutanes. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Zachary X Giustra, Xinyu Yang, Min Chen, Holger F Bettinger, Shih-Yuan Liu. Accessing 1,2-Substituted Cyclobutanes through 1,2-Azaborine Photoisomerization. Angewandte Chemie (International ed. in English). 2019 Dec 19;58(52):18918-18922
PMID: 31604006
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