Dithieno[1,4]thiazines and Bis[1]benzothieno[1,4]thiazines-Organometallic Synthesis and Functionalization of Electron Density Enriched Congeners of Phenothiazine.

Lars May, Thomas J J Müller

Molecules (Basel, Switzerland) 2020 May 07

filter terms:

This mini-review summarizes the syntheses and functionalizations of dithieno[1,4]thiazines and bis[1]benzothieno[1,4]thiazines, both electron density-enriched congeners of phenothiazines with remarkable electronic properties. Diversity-oriented, straightforward, and efficient syntheses, including versatile one-pot processes, have been developed for the anellated 1,4-thiazines as well as various functionalization for the expansion of the π-systems. Thereby, syntheses of different regioisomers depending on the (benzo)thieno-thiazine anellation are discussed, which exert a deep impact on the electronic properties. The tunable photophysical and electrochemical properties of dithieno[1,4]thiazines and bis[1]benzothieno[1,4]thiazines outscore phenothiazines on many points and promise an enormous potential in molecular electronics and applications beyond.

Citation

Lars May, Thomas J J Müller. Dithieno[1,4]thiazines and Bis[1]benzothieno[1,4]thiazines-Organometallic Synthesis and Functionalization of Electron Density Enriched Congeners of Phenothiazine. Molecules (Basel, Switzerland). 2020 May 07;25(9)