Correlation Engine 2.0
Clear Search sequence regions

filter terms:
  • 1 5- cod (3)
  • diphenyl (1)
  • diphenyl (1)
  • ligand (6)
  • nickel (4)
  • Sizes of these terms reflect their relevance to your search.

    Addition of sub-stoichiometric quantities of PEt3 and diphenyl disulfide to a solution of [Ni(1,5-cod)2 ] generates a mixture of [Ni3 (SPh)4 (PEt3 )3 ] (1), unreacted [Ni(1,5-cod)2 ], and [(1,5-cod)Ni(PEt3 )2 ], according to 1 H and 31 P{1 H} NMR spectroscopic monitoring of the in situ reaction mixture. On standing, complex 1 converts into [Ni4 (S)(Ph)(SPh)3 (PEt3 )3 ] (2), via formal addition of a "Ni(0)" equivalent, coupled with a CS oxidative addition step, which simultaneously generates the Ni-bound phenyl ligand and the μ3 -sulfide ligand. Upon gentle heating, complex 2 converts into a mixture of [Ni5 (S)2 (SPh)2 (PEt3 )5 ] (3) and [Ni8 (S)5 (PEt3 )7 ] (4), via further addition of "Ni(0)" equivalents, in combination with a series of C-S oxidative addition and CC reductive elimination steps, which serve to convert thiophenolate ligands into sulfide ligands and biphenyl. The presence of 1-4 in the reaction mixture is confirmed by their independent syntheses and subsequent spectroscopic characterization. Overall, this work provides an unprecedented level of detail of the early stages of Ni nanocluster growth and highlights the fundamental reaction steps (i.e., metal atom addition, CS oxidative addition, and CC reductive elimination) that are required to grow an individual cluster. © 2020 Wiley-VCH GmbH.


    Alexander J Touchton, Guang Wu, Trevor W Hayton. Understanding the Early Stages of Nickel Sulfide Nanocluster Growth: Isolation of Ni3 , Ni4 , Ni5 , and Ni8 Intermediates. Small (Weinheim an der Bergstrasse, Germany). 2021 Jul;17(27):e2003133

    Expand section icon Mesh Tags

    Expand section icon Substances

    PMID: 32954670

    View Full Text