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Two crystalline open-framework indium phosphites (denoted SCU-31 and SCU-32) were prepared using amino acids as structure-directing agents. They have isoreticular pillared-layered structures built up from 6 × 1 and 4 = 1 clusters. Notably, the two compounds show excellent water stability and exhibit blue fluorescence under UV light irradiation at room temperature. The proton-conducting behaviour of SCU-31 was also investigated.


Yumei Mao, Yuandan Deng, Lindong Luan, Hongmei Zeng, Guohong Zou, Zhien Lin. Pillared-layered indium phosphites templated by amino acids: isoreticular structures, water stability, and fluorescence. Dalton transactions (Cambridge, England : 2003). 2020 Nov 14;49(42):14766-14770

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PMID: 33030173

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