Measurement and Correlation of the Thermal Conductivity of cis-1,1,1,4,4,4-hexafluoro-2-butene.

New experimental data for the thermal conductivity of cis-1,1,1,4,4,4-hexafluoro-2-butene (R-1336mzz(Z)) are reported for vapor, liquid and supercritical states. These data were obtained with transient hot-wire apparatus over the temperature range from 192 K to 498 K and at pressures from 0.05 MPa to 69 MPa. These data were used to develop a wide-range correlation for the thermal conductivity of the vapor, liquid, and supercritical fluid. The experimental data reported here have an uncertainty of 1 % for the liquid and supercritical regions (densities above 600 kg·m-3), 1.5 % for vapor and supercritical regions (pressures greater than or equal to 1 MPa and densities less than 200 kg·m-3), 3 % for supercritical states (densities between 200 kg·m-3 and 600 kg·m-3), and 3 % for vapor and supercritical states (pressures below 1 MPa). The thermal-conductivity correlation developed in this work is estimated to have an expanded relative uncertainty, at a 95 % confidence level, ranging from approximately 1.4 % to 4.2 % depending on the temperature and pressure, with larger uncertainties in the critical region.

Citation

Richard A Perkins, Marcia L Huber. Measurement and Correlation of the Thermal Conductivity of cis-1,1,1,4,4,4-hexafluoro-2-butene. International journal of thermophysics. 2020;41

PMID: 33311827

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