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A pair of structurally-similar and stable 8-coordinate high-spin Fe(ii) and Fe(iii) compounds have been obtained. Both compounds exhibit field-induced slow magnetic relaxation behaviour. The Fe(iii) compound represents the first example of 8-coordinate Fe(iii) single-molecule magnets (SMM).

Citation

Qian-Qian Su, Qiong Yuan, Xiao-Fan Wu, Si-Huai Chen, Jing Xiang, Xin-Xin Jin, Li-Xin Wang, Bing-Wu Wang, Song Gao, Tai-Chu Lau. Slow magnetic relaxation in structurally similar mononuclear 8-coordinate Fe(II) and Fe(III) compounds. Chemical communications (Cambridge, England). 2021 Jan 26;57(6):781-784


PMID: 33355553

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