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    An allylarylation of electron-deficient alkenes with aryl boronates and allylic carbonates has been developed. This method allows access to a wide variety of carbon skeletons from readily available starting materials. Mechanistic studies indicate that this reaction is enabled by a cooperative catalysis based on merging Pd0 /PdII redox and PdII /PdII non-redox catalytic cycles. © 2021 Wiley-VCH GmbH.


    Kazuhiko Semba, Naoki Ohta, Fritz Paulus, Masaki Ohata, Yoshiaki Nakao. Merging Pd0 /PdII Redox and PdII /PdII Non-redox Catalytic Cycles for the Allylarylation of Electron-Deficient Alkenes. Chemistry (Weinheim an der Bergstrasse, Germany). 2021 Mar 12;27(15):5035-5040

    PMID: 33442926

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