We report the dioxygenation of mesoionic N-heterocyclic olefins (mNHOs) using molecular dioxygen. For 1,2,3-triazole-derived mNHOs possessing a vinyl proton and at least one acidic C-H group, they are oxidized into the corresponding triazolium benzoate salts, whereas those without vinyl proton or an acidic C-H group are oxidized into triazolium oxide and ketones/aldehydes.
Qiuming Liang, Kasumi Hayashi, Longfei Li, Datong Song. Dioxygenation of unprotected mesoionic N-heterocyclic olefins. Chemical communications (Cambridge, England). 2021 Oct 19;57(83):10927-10930
PMID: 34596194
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