Xin Chen, Han Wang, Youchao Liu, Yang Zhou, Weiqi Huang, Minjuan Li, Yanqiang Li, Yangxin Chen, Sangen Zhao, Junhua Luo
Chemistry (Weinheim an der Bergstrasse, Germany) 2021 Dec 20Discovering new functional genes and developing high-performance materials are the goals being pursued by scientists. In this work, we successfully obtained a second-order nonlinear optical (NLO) material via the aqueous solution method, Y[N(CN)2 ]4 [NH(C2 H5 )3 ] ⋅ 3H2 O, which is the first NLO material with the anionic group N(CN)2 - . Remarkably, this material is not only strongly NLO-active at 1064 nm with a response of about 2.8 × KH2 PO4 , but also possesses a short UV absorption edge of 250 nm. In-depth first-principles calculations illustrate well that the optical properties are mainly from the strong interaction of N, C and Y atoms. This result indicates that the N(CN)2 - anion may be a new NLO functional gene. This work enriches the diversity of NLO functional genes and materials. © 2021 Wiley-VCH GmbH.
Xin Chen, Han Wang, Youchao Liu, Yang Zhou, Weiqi Huang, Minjuan Li, Yanqiang Li, Yangxin Chen, Sangen Zhao, Junhua Luo. A New Nonlinear Optical Material with N(CN)2 - Anion. Chemistry (Weinheim an der Bergstrasse, Germany). 2021 Dec 20;27(71):17769-17772
PMID: 34670000
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