Facile Synthesis of Amorphous MoCo Lamellar Hydroxide for Alkaline Water Oxidation.

To find an oxygen evolution reaction (OER) catalyst with satisfactory catalytic performance and affordable cost is of great importance to the development of many new energy devices. In this work, a simple and effective strategy was developed to synthesize a series of amorphous MoCo lamellar hydroxide through one-step chemical co-precipitation. Systematic investigations showed that different functional agents (2-methylimidazole, NaOH, NH4 OH) in the fabrication process resulted in different micromorphology of the catalyst, thus influencing its electrocatalytic performance. Also, adding various amounts of Mo could influence the intrinsic catalytic properties. Samples synthesized with appropriate functional agent addition and optimized Mo addition exhibited amorphous nature and bent nanosheet morphology, as well as highest intrinsic catalytic activity, showing a low overpotential of 290 mV at 10 mA cm-2 and a small Tafel slope of 55 mV dec-1 in 1 m KOH solution. Additionally, the catalytic performance of the sample showed just small decay after 50 h chronopotentiometry test and 3000 cyclic voltammetry cycles, exhibiting the ultra-stable catalytic activity of the catalyst. This work provides a possible large-scale commercial production strategy of OER catalysts with promising performance and low fabrication cost. © 2021 Wiley-VCH GmbH.

Citation

Shengtai Qian, Gang Huang, Tong Zhu, Yue Zhang, Wukui Tang, Ronghai Yu. Facile Synthesis of Amorphous MoCo Lamellar Hydroxide for Alkaline Water Oxidation. ChemSusChem. 2022 Jan 10;15(1):e202101666

PMID: 34738738

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