Self-assembled supramolecule for synthesizing highly thermally conductive Cellulose/Carbon nitride nanocomposites with improved flame retardancy.

Hangzhen Zhang, Kun Wu, Enxiang Jiao, Yingchun Liu, Jun Shi, Mangeng Lu

Journal of colloid and interface science 2022 Feb 15

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The fabrication of polymer composites with excellent thermal conductivity typically involves complex matrix or fillers modifications. This study proposed a simple technique based on precursor selection for obtaining highly thermally conductive cellulose nanofiber (CNF)/supramolecule-synthesized carbon nitride (SCN) composites. Fourier-transform infrared tests demonstrated the construction of hydrogen bonds between CNF and SCN; a highly ordered structure and relatively compact in-plane stacking were confirmed via scanning electron microscopy and X-ray diffraction characterizations. Consequently, the resultant CNF/SCN composites exhibited remarkable in-plane thermal conductivity of 11.83 ± 0.41 W m-1 K-1 at 30 wt% SCN content, which was attributed to the significantly reduced interfacial phonon scattering. It also showed evident improvements in electrical insulation and flame retardancy compared with the pure CNF film, where the volume resistivity, peak heat release rate, and total heat release were remarkably enhanced by 1242% and reduced by 59.9% and 15.8%, respectively. Further analysis of char residuals revealed a relatively dense surface, high concentration of carbon materials, and a high degree of graphitization, indicating that the char residual functioned as a robust physical barrier to effectively inhibit combustion. This study provides a facile approach to achieving high-efficiency improvements in thermal conductivity and flame retardancy, and simultaneously facilitating broader applications of carbon nitride in thermal management. Copyright © 2021 Elsevier Inc. All rights reserved.

Citation

Hangzhen Zhang, Kun Wu, Enxiang Jiao, Yingchun Liu, Jun Shi, Mangeng Lu. Self-assembled supramolecule for synthesizing highly thermally conductive Cellulose/Carbon nitride nanocomposites with improved flame retardancy. Journal of colloid and interface science. 2022 Feb 15;608(Pt 3):2560-2570