Stable thiolate adducts of Rh2(OAc)4 - assembly of hexametallic Ni4Rh2 complexes.

Sara Schmorl, Martin Börner, Berthold Kersting

Dalton transactions (Cambridge, England : 2003) 2021 Dec 20

filter terms:

all
compound
phenotype
gene and proteins

Thiolate adducts of dirhodium(II) tetraacetate have proven difficult to prepare. We isolated a stable, paramagnetic Ni4Rh2 adduct containing Ni-based metallothiolates bound in axial positions of the Rh24+ core. The adduct formation is accompanied by a change of the magnetic exchange interaction in the dinuclear Ni2 subunits.

Citation

Sara Schmorl, Martin Börner, Berthold Kersting. Stable thiolate adducts of Rh2(OAc)4 - assembly of hexametallic Ni4Rh2 complexes. Dalton transactions (Cambridge, England : 2003). 2021 Dec 20;51(1):59-62

PMID: 34889331

View Full Text