Hard-Cation-Soft-Anion Ionic Liquids for PEDOT:PSS Treatment.

Changwon Choi, Ambroise de Izarra, Ikhee Han, Woojin Jeon, Yves Lansac, Yun Hee Jang

The journal of physical chemistry. B 2022 Feb 24

filter terms:

A promising conducting polymer poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) experiences significant conductivity enhancement when treated with proper ionic liquids (ILs). Based on the hard-soft-acid-base principle, we propose a combination of a hydrophilic hard cation A+ (instead of the commonly used 1-ethyl-3-methyl imidazolium, EMIM+) and a hydrophobic soft anion X- (such as tetracyanoborate, TCB-) as the best ILs for this purpose. Such ILs would decouple hydrophilic-but-insulating PSS- from conducting-but-hydrophobic PEDOT+ most efficiently by strong interactions with hydrophilic A+ and hydrophobic X-, respectively. Such a favorable ion exchange between PEDOT+:PSS- and A+:X- ILs would allow the growth of conducting PEDOT+ domains decorated by X-, not disturbed by PSS- or A+. Using density functional theory calculations and molecular dynamics simulations, we demonstrate that a protic cation- (aliphatic N-alkyl pyrrolidinium, in particular) combined with the hydrophobic anion TCB- indeed outperforms EMIM+ by promptly leaving hydrophobic TCB- and strongly binding to hydrophilic PSS-.

Citation

Changwon Choi, Ambroise de Izarra, Ikhee Han, Woojin Jeon, Yves Lansac, Yun Hee Jang. Hard-Cation-Soft-Anion Ionic Liquids for PEDOT:PSS Treatment. The journal of physical chemistry. B. 2022 Feb 24;126(7):1615-1624