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For engineering implementation of an ultralow-surface-energy hierarchically micro/nanostructured topography for superomniphobic surfaces, a strategy involving the design of a partially open-cage fluorinated polyhedral oligomeric silsesquioxane bearing an -OH pair (poc-F13POSS-2OH) and the subsequent wrapping of nanoparticles with poc-F13POSS-2OH as a result of weak-acid-triggered -OH protonation is developed. The poc-F13POSS-wrapped nanoparticle-based surfaces showed broad-spectrum superomniphobicity. This work has advanced the engineering of state-of-the-art superomniphobic solid surfaces/interfaces.


Boxu Chen, Mingjin Yang, Xilin Lin, Wenfeng Liu, Hai Yuan, Jingwen Liao. Strategy toward fluorinated polyhedral oligomeric silsesquioxane wrapping nanoparticles for superomniphobic surfaces. Chemical communications (Cambridge, England). 2022 Mar 29;58(26):4263-4266

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PMID: 35289826

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