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    A palladium-catalyzed Heck/carbonylative cyclization process has been explored for the synthesis of functionalized amides. By using nitroarenes as readily accessible nitrogen sources, a variety of amide products were obtained in moderate to excellent yields with good functional group compatibility. Furthermore, a late-stage modification of a natural molecule is also achieved by this protocol.


    Ren-Rui Xu, Dan Wen, Xinxin Qi, Xiao-Feng Wu. Palladium-catalyzed cascade Heck-type cyclization and reductive aminocarbonylation for the synthesis of functionalized amides. Organic & biomolecular chemistry. 2022 Mar 30;20(13):2605-2608

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    PMID: 35293928

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