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    Herein, a new NIR photoredox catalyst, bridged eosin Y (BEY), has been developed. Its detailed structure and NIR optical properties are clarified by using various spectroscopic methods, X-ray single-crystal structure analysis and DFT calculations. In addition, we demonstrate the photoreaction in colored reagents and high-concentration suspensions to show the advantage of NIR photoredox-catalyzed reactions.


    Masaru Tanioka, Ayako Kuromiya, Rina Ueda, Tohru Obata, Atsuya Muranaka, Masanobu Uchiyama, Shinichiro Kamino. Bridged eosin Y: a visible and near-infrared photoredox catalyst. Chemical communications (Cambridge, England). 2022 Jul 12;58(56):7825-7828

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    PMID: 35748437

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