Correlation Engine 2.0
Clear Search sequence regions


  • carbonates (3)
  • cycle life (1)
  • divinyl (9)
  • electrolytes (2)
  • gas (7)
  • ion (6)
  • lithium (7)
  • power supplies (1)
  • research (1)
  • sulfones (2)
  • Sizes of these terms reflect their relevance to your search.

    The focus of mainstream lithium-ion battery (LIB) research is on increasing the battery's capacity and performance; however, more effort should be invested in LIB safety for widespread use. One aspect of major concern for LIB cells is the gas generation phenomenon. Following conventional battery engineering practices with electrolyte additives, we examined the potential usage of electrolyte additives to address this specific issue and found a feasible candidate in divinyl sulfone (DVSF). We manufactured four identical battery cells and employed an electrolyte mixture with four different DVSF concentrations (0%, 0.5%, 1.0%, and 2.0%). By measuring the generated gas volume from each battery cell, we demonstrated the potential of DVSF additives as an effective approach for reducing the gas generation in LIB cells. We found that a DVSF concentration of only 1% was necessary to reduce the gas generation by approximately 50% while simultaneously experiencing a negligible impact on the cycle life. To better understand this effect on a molecular level, we examined possible electrochemical reactions through ab initio molecular dynamics (AIMD) based on the density functional theory (DFT). From the electrolyte mixture's exposure to either an electrochemically reductive or an oxidative environment, we determined the reaction pathways for the generation of CO2 gas and the mechanism by which DVSF additives effectively blocked the gas's generation. The key reaction was merging DVSF with cyclic carbonates, such as FEC. Therefore, we concluded that DVSF additives could offer a relatively simplistic and effective approach for controlling the gas generation in lithium-ion batteries.

    Citation

    Woon Ih Choi, Insun Park, Jae Sik An, Dong Young Kim, Meiten Koh, Inkook Jang, Dae Sin Kim, Yoon-Sok Kang, Youngseon Shim. Controlling Gas Generation of Li-Ion Battery through Divinyl Sulfone Electrolyte Additive. International journal of molecular sciences. 2022 Jun 30;23(13)

    Expand section icon Mesh Tags

    Expand section icon Substances


    PMID: 35806333

    View Full Text