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An original and facile method for the generation of β-naphtha-1-thioquinones using DAST and 2-naphthols has been developed. A series of dehydro-2-naphthol-1-sulphides or naphtha-oxathiane derivatives were synthesized by in situ Diels-Alder cycloaddition reactions of β-naphtha-1-thioquinone with itself or various alkenes.

Citation

Yang Geng, Xianying Gao, Apeng Liang, Jingya Li, Dapeng Zou, Yangjie Wu, Yusheng Wu. 4 + 2] cycloaddition reactions of β-naphtha-1-thioquinones generated from 2-naphthols and DAST. Organic & biomolecular chemistry. 2022 Aug 31;20(34):6750-6754

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PMID: 35938985

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