Clear Search sequence regions


Sizes of these terms reflect their relevance to your search.

In this paper, we report a novel surface-enhanced Raman spectroscopy (SERS) substrate based on hierarchical β-Bi2O3/Au2Ag2 microspheres for rapid, sensitive and selective detection of environment pollutants including o-dianisidine (o-diASD) and Hg2+ in environmental samples. The sheet-like β-Bi2O3 not only provides large specific surface areas for adsorption of molecules and AuAg, but also emerges as semiconductor matrix with chemical enhancement combined with AuAg with electromagnetic enhancement, making promising SERS activity. Particularly, the β-Bi2O3/Au2Ag2 shows high SERS performance for 4-mercaptobenzoic acid and TMB with minimum detectable concentration of 0.1 μg/L with enhancement factor of 3.1 × 107 and 6.3 × 107, respectively. The density functional theory simulations were further adopted to explain the high SERS activity and selectivity for o-diASD and TMB. Finally, the β-Bi2O3/Au2Ag2 was applied to direct detection of o-diASD, and indirect detection of Hg2+ by TMB marking in environmental samples. The linearity range of 0.5-200.0 and 0.2-500.0 μg/L with limit of detection of 0.2 and 0.07 μg/L for o-diASD and Hg2+ ions can be achieved, respectively. This method provides a novel strategy in designing and fabricating SERS substrates with high performance for rapid, sensitive and accurate analysis of environmental pollutants. Copyright © 2022 Elsevier B.V. All rights reserved.

Citation

Kun Ge, Yihong Huang, Hanqiang Zhang. Fabrication of hierarchical β-Bi2O3/AuAg microspheres for sensitive, selective and rapid detection of environment pollutants by surface-enhanced Raman spectroscopy. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy. 2023 Jan 15;285:121907

Expand section icon Mesh Tags

Expand section icon Substances


PMID: 36179562

View Full Text