Nickel-Catalyzed Aminocarbonylation of Aryl Iodides with 1 atm CO.

Ning Liu, Xianqing Wu, Jingping Qu, Yifeng Chen

Chemistry, an Asian journal 2023 Jan 03

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Reported here is a nickel-catalyzed aminocarbonylation of aromatic iodides with (hetero)aryl anilines and alkyl amines under atmospheric CO pressure. The reaction features with broad substrate scope with excellent functional group tolerance, providing an expedient method for the construction of amide analogues. Notably, amino alcohols can be selectively transformed into the corresponding amides successfully without interfering the hydroxyl group under the current standard conditions. © 2022 Wiley-VCH GmbH.

Citation

Ning Liu, Xianqing Wu, Jingping Qu, Yifeng Chen. Nickel-Catalyzed Aminocarbonylation of Aryl Iodides with 1 atm CO. Chemistry, an Asian journal. 2023 Jan 03;18(1):e202201061