Efficient Rechargeable Li-CO2 Battery with a Liquid Electrolyte-Soluble CuCl2 Electrocatalyst.

We demonstrate here a simple liquid electrolyte soluble Cu-compound, viz., cupric chloride (CuCl2) as an alternative electrocatalyst for nonaqueous Li-CO2 batteries. The key point behind the selection of CuCl2 is that the theoretical potential of Li-CO2 batteries (≈2.8 V; Li+|Li) lies within the Cu1+|Cu0 redox couple (2.3-3.3 V; Li+|Li). The presence of CuCl2 in the liquid electrolyte near to the carbon nanotubes (≡ coelectrocatalyst)-loaded porous-CO2 cathode led to efficient electrocatalysis of CO2 and superior Li-CO2 battery performance. The cell overpotential in the presence of CuCl2 is 0.65 V, which is less than half compared to the one without it (≈1.7 V). Extensive investigations precisely elucidate the electrocatalytic mediation of CuCl2 with the redox characteristics of CO2. Additionally, only in the presence of CuCl2, the existence of Li-oxalate (Li2C2O4) is detected, which is a seldomly reported intermediate preceding the formation of Li2CO3.

Citation

Abhishek Bharti, Govindaraj Achutharao, Aninda J Bhattacharyya. Efficient Rechargeable Li-CO2 Battery with a Liquid Electrolyte-Soluble CuCl2 Electrocatalyst. ACS applied materials & interfaces. 2023 Nov 22;15(46):53342-53350

PMID: 37939266

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