Europium-doped cerium oxide nanoparticles: investigating oxygen vacancies and their role in enhanced photocatalytic and magnetic properties.

Ankita Ankita, Surjeet Chahal, Saurabh Singh, Sandeep Kumar, Parmod Kumar

Environmental science and pollution research international 2024 Jan

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In this study, pure and europium-doped (2%, 4%, 6%, and 8%) cerium oxide (CeO2) nanoparticles (NPs) were employed for efficient dye removal through photocatalytic approach. XRD and TEM confirmed the formation of pure CeO2 nanoparticles, while XPS and Raman spectroscopy were used to analyze the electronic properties and lattice defects, such as oxygen vacancies. The presence of lattice defects, which increased with the concentration of Eu, was found to be responsible for the enhanced degradation of Rose Bengal dye (82.4% for 8% Eu-doped sample) in 75 min. FTIR confirmed the chemical composition of the synthesized sample. The band at 617 cm-1, corresponding to the symmetrical stretching vibration mode of (Ce-O-Ce) or (Ce-O-Eu). The magnetic properties of synthesized samples were examined using VSM, revealing an increase from 4.48 to 11.0 emu/g in magnetization. This enhancement was attributed to F-center exchange mechanism (FCE), resulting from the presence of oxygen vacancies. These findings contribute to the development of advanced materials for sustainable wastewater treatment and spintronics. © 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.

Citation

Ankita Ankita, Surjeet Chahal, Saurabh Singh, Sandeep Kumar, Parmod Kumar. Europium-doped cerium oxide nanoparticles: investigating oxygen vacancies and their role in enhanced photocatalytic and magnetic properties. Environmental science and pollution research international. 2024 Jan;31(1):1276-1287