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Pillar[5]arene-segregated ion pairs for enhanced cycloaddition of epoxides with CO2.
Yidan Zhou, Zejiang Liu, Zhiyao Yang, Yuexuan Zheng, Maoxia Yang, Wen Feng, Xiaowei Li, Lihua Yuan
Chemical communications (Cambridge, England) 2024 Jan 02Sizes of these terms reflect their relevance to your search.
A supramolecular approach using a polyviologen-pillar[5]arene complex as segregated ion pairs was shown to be highly efficient for the conversion of CO2 with epoxides into cyclic carbonates without the need for metals or solvents. The enhanced catalytic performance was achieved by cooperative ion pair segregation and CO2 fixation.
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Yidan Zhou, Zejiang Liu, Zhiyao Yang, Yuexuan Zheng, Maoxia Yang, Wen Feng, Xiaowei Li, Lihua Yuan. Pillar[5]arene-segregated ion pairs for enhanced cycloaddition of epoxides with CO2. Chemical communications (Cambridge, England). 2024 Jan 02;60(3):300-303
PMID: 38054763
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