Jing Fang, Dongyue An, Weinan Chen, Si Liu, Xuefeng Lu, Gang Zhou
The Journal of organic chemistry 2024 Apr 05Three new donor-acceptor-donor (D-A-D) architecture regioisomers comprising a large planar electron-withdrawing core tribenzo[a,c,i]phenazine and two identical electron-donating triphenylamines with different substitution patterns were designed and synthesized. Employing this regioisomerization strategy, the intramolecular charge-transfer interactions are effectively tuned and result in a significant bathochromic shift of photoluminescence maximum over 100 nm, which induces the corresponding emission band extending into the near-infrared region as well as giving a high solid-state quantum yield of 25%. Meanwhile, it is found that the supramolecular interactions of this series of regioisomers with planar electron-donor pyrene are greatly affected by the substitution pattern.
Jing Fang, Dongyue An, Weinan Chen, Si Liu, Xuefeng Lu, Gang Zhou. Manipulating Intramolecular Charge Transfer and Supramolecular Interaction in D-A-D Conjugated Systems by Regioisomerization. The Journal of organic chemistry. 2024 Apr 05;89(7):4523-4529
PMID: 38502930
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